HS 28332500

Copper Sulphate

Copper Sulphate, in its pentahydrate form CuSO4 5H2O with CAS number 7758-99-8, is the most widely used soluble copper compound in industry and agriculture. It is the deep blue crystalline solid historically known as blue vitriol or bluestone.

The pentahydrate contains approximately 25.5 percent copper and dissolves freely in water to give a clear blue solution. Its combination of low cost, high solubility, and broad-spectrum antimicrobial activity supports applications from vineyard spraying to electroplating to animal nutrition.

We source bulk Copper Sulphate from top China manufacturers for our partners. The manufacturers are in Jiangsu. A smaller requirement can ship in a combined container with other ingredients.

Please send the grade you need, the volume and your destination port, and we will come back with a solution and a price.

or call +86-21-6858 0751

Copper Sulphate
Packaging
25 kg kraft paper bag with PE inner liner
  • ISO 9001
  • HACCP
  • Halal
  • Kosher

Specifications

Grades / Types Available: food grade

ItemSpecification
AppearanceBlue crystalline granules
Assay (CuSO₄·5H₂O)≥ 99.0%
Copper Content≥ 25.0%
Iron≤ 0.003%
Heavy Metals (as Pb)≤ 10 mg/kg
Arsenic≤ 3 mg/kg
GradeN/A
Purity/Assay98.0-102.0
Substances Not Precipitated by Hydrogen Sulfide0.3
Lead (Pb)0.0004

Common Markets Grades

Several grades of Copper Sulphate exist, distinguished by purity, particle size, and end-use sector.

Pharmaceutical grade meets USP and Ph. Eur. monographs at 99.0 to 100.5 percent assay on the dried basis, with controls on lead, arsenic, iron, and substitutionable cations. This grade serves injectable copper supplementation and ophthalmic preparations.

Feed grade is graded at 25 percent copper minimum, in fine crystal or granular form, for inclusion in poultry, swine, and ruminant premixes.

Agricultural grade is the largest-volume category, sold as fine crystal, snow, or granular product for tank-mixed foliar sprays, Bordeaux mixture preparation, and seed treatment.

Electroplating grade is graded at 99 percent minimum, with tight chloride and iron specifications, for use in copper electrowinning and printed circuit board manufacturing.

Anhydrous CuSO4, a white powder, is produced for laboratory use as a water indicator and for specialty chemical synthesis.

Applications

  • Vineyard, orchard, and vegetable fungicide as Bordeaux mixture (CuSO4 plus lime)
  • Seed treatment for cereals to control bunt and smut diseases
  • Algaecide in irrigation canals, reservoirs, and ornamental ponds
  • Animal feed micronutrient for poultry, swine, dairy, and aquaculture
  • Hoof rot prevention in cattle and sheep through foot baths
  • Copper electrowinning and refining cells
  • Printed circuit board manufacturing as the primary copper plating bath constituent
  • Mordant in textile dyeing and printing
  • Wood preservative formulations (alkaline copper quat)
  • Pharmaceutical preparations including copper deficiency injectables
  • Analytical chemistry as a Fehling reagent constituent and water indicator

China Manufacturers of Copper Sulphate

Top Copper Sulphate manufacturers in China.

Company names and logos are the property of the manufacturers themselves. They are listed here because our own directory records them as producing this ingredient. A listing is not an endorsement by them, and we do not represent them or speak on their behalf.

How We Help Source Copper Sulphate

  • Direct Factory Sourcing

    We run the whole process: selecting the manufacturer from the top Chinese food ingredient producers, negotiating the price, verifying quality, and coordinating the logistics. You deal with us instead of with several factories at once.

  • Original Packaging and Documents from the Manufacturer

    The manufacturer sends your Copper Sulphate out of its own factory in the original packing, through to your destination port. The COA, COO, MSDS, TDS and any certifications reach you from the manufacturer as well.

  • Free Samples and Lead Time

    We send 100 to 500 g free for your own laboratory to test and you cover only the courier, usually within 2 to 3 working days. ETD is usually within 7 to 15 days once the order is confirmed, and we check that date against the factory's own manufacturing schedule before we give it to you.

  • Combined Shipment

    We can load Copper Sulphate together with other ingredients such as Sodium Acetate, Calcium Citrate and Sodium Lactate into one 20' FCL. If your quantity is small, we can also ship LCL.

Regulatory Status

Copper Sulphate carries clearance across food, feed, agricultural, and pharmaceutical channels.

The U.S. Environmental Protection Agency registers Copper Sulphate as a fungicide, algaecide, herbicide, and antimicrobial under FIFRA. The U.S. Food and Drug Administration affirms it as GRAS for use as a nutrient under 21 CFR 184.1261 and approves it in animal feed under 21 CFR 582.80.

In the European Union, Regulation (EC) No 1107/2009 authorises copper compounds including copper sulphate pentahydrate as plant protection actives, with maximum application rates set to manage soil copper accumulation. Regulation (EC) No 1831/2003 permits the same compound as a nutritional feed additive.

For food supplement use, Annex II of Directive 2002/46/EC lists Copper Sulphate. The U.S. Pharmacopeia carries a monograph for Cupric Sulphate, and the European and British Pharmacopoeias carry equivalent monographs.

Halal and Kosher certifications exist because the production chain is fully inorganic.

Manufacturing Process

Copper Sulphate is produced industrially by reacting a copper source with sulphuric acid.

The dominant route uses copper scrap or copper cathode dissolved in dilute sulphuric acid with sparged air to provide the oxidising equivalent. The reaction proceeds at 60 to 90 degrees Celsius until a saturated blue liquor is reached.

An alternative route, used where copper oxide ore or roasted copper concentrate is produced, leaches the oxidised ore directly with sulphuric acid. The liquor is purified by selective precipitation of iron, arsenic, and other impurities at controlled pH.

The purified liquor is evaporated and crystallised. The pentahydrate crystallises below 60 degrees Celsius as the familiar deep blue prismatic crystals. Above 100 degrees Celsius, water is lost stepwise to give the trihydrate and monohydrate, and complete dehydration to anhydrous CuSO4 occurs above 250 degrees Celsius.

Electrowinning sludges and spent etching liquors from electronics manufacturing are major secondary sources for agricultural and feed grade material.